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Doc Brown's chemistry notes on atomic and electron structure

2. The Bohr model 'portrait' of an atom, how the three fundamental particles fit together in atomic structure and comparing the relative size of particles


[Author © Dr Phil Brown GRIC, PhD: Doc Brown's chemistry exam revision notes on an atomic model suitable for students of UK GCSE/A advanced level and international IGCSE/O/Advanced A level chemistry courses, ~US grades 9-12 chemistry notes  [page updated RE-EDIT]

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 INDEX of atomic structure exam revision notes


2. What can we say about 'A Portrait of an Atom'?

Images of what you normally can't see! Size comparison of atoms, molecules and cells!

The picture of 'atomic structure, illustrated below is the result of many developing 'atomic theory' backed up by successive generations of experimental results. This is the best picture we have (at least for GCSE and A-Level chemistry courses!).

Bohr model of an atom, electronic diagram for lithium

All the terms and notation are explained in later sections.

However this diagram, which is based on the Bohr model of atomic structure, although more realistic in terms of the real size of the nucleus compared to the atom as a whole, so it is not convenient to give a brief diagrammatic picture of the composition of an atom.

The central nucleus of protons and neutrons (most of the mass of an atom) is extremely small even compared to the size of an atom. The rest of the 'almost empty space' of an atom is occupied by the negative electrons, held by, and moving around the positive nucleus in their energy levels or 'shells'.

The electrons are also pretty tiny in mass too, compared to a proton or neutron, but the volume the electrons and their energy levels occupy, determines the size of the atom, but an atom mainly empty space with the nucleus at the centre!

Bohr theorised the negative electrons can only exist in certain specific energy levels (shells) held in place by the positive nucleus (see section on the history of development of the atomic model). These are shown in the above diagram, but fully explained in later sections.

All of these theories must, and have been, backed up by repeated and varied experiments.

As each new experiment was/is done, it must support the current theory or the theory needs to be modified to take into account new discoveries.

Some of these important experiments are described further down the page.

Even new experimental findings written up in research papers should be thoroughly peer reviewed, that is checked by scientists of at least equal academic ranking to the researchers. That's how science works!

 

The size of an atom compared to other 'particles'

The size of an individual atom is around 0.1 nm or 1 x 10-10 m

and the size of the nucleus itself is only about 1 x 10-14 m, about 1/10000th of the radius of the atom.

(nm = nanometres, 1 nm = 10-9 m).

Most of the mass is in the centre of the atom, that is the nucleus, which has a radius of around 1/10000th of the whole atom!

This means the radius of the nucleus is about 1 x 10-14 m (0.00001 nm), pretty small !!, but still consists of most of the mass of an atom!!!

If you look at the table of size comparison below,

its not until you get to a human hair can we see clearly something with the naked eye. The width of a human hair is approximately 106 times that of an atom (a million times bigger) and 1010 times bigger than a nucleus (ten thousand million times bigger).

You can of course see cells under examination with an optical microscope, but these are over 500 000 times bigger than an individual atom. You can, however, observe atoms using an electron microscope.

A comparison data table of particles sizes/dimensions

Examples of atoms, molecules, nanoparticles and other 'things'

material nucleus carbon atom sulphur atom water molecule silver atom glucose sugar molecule typical small protein silver or titanium dioxide nano-particles typical virus e.g. cold virus a typical carbon nanotube a typical bacteria a typical eukaryotic cell width of human hair
Symbol-formula na C S H2O Ag C6H12O6 na Agn

(TiO2)n

na Cn na na na
Size in nm - diameter or length 0.00001 0.16 0.2 0.2 0.28 0.3 x 0.6 5-10 35-120 30-50 100 x 6 5000 50000 50000- 100000
longest length or diameter m 1 x

10-14

1.6 x

10-10

 2 x

10-10

2

x 10-10

 2.8 x

10-10

6 x 10-10

x

3 x 10-10

5-10

x 10-9

 3.5-12

x 10-8

3-5

x 10-8

1

x 10-7

5

x 10-6

5

x 10-5

0.5 to 1.0

x 10-4

na means not applicable


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